Gibbs’ paradox according to Gibbs and slightly beyond

نویسندگان

چکیده

برای دانلود باید عضویت طلایی داشته باشید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Gibbs Paradox and Similarity Principle

As no heat effect and mechanical work are observed, we have a simple experimental resolution of the Gibbs paradox: both the thermodynamic entropy of mixing and the Gibbs free energy change are zero during the formation of any ideal mixtures. Information loss is the driving force of these spontaneous processes. Information is defined as the amount of the compressed data. Information losses due t...

متن کامل

Beyond Gibbs-Boltzmann-Shannon: general entropies—the Gibbs-Lorentzian example

*Correspondence: Rudolf A. Treumann, International Space Science Institute, Hallerstrasse 6, CH-3012 Bern, Switzerland e-mail: [email protected] We propose a generalization of Gibbs’ statistical mechanics into the domain of non-negligible phase space correlations. Derived are the probability distribution and entropy as a generalized ensemble average, replacing Gibbs-Boltzmann-Shannon’s entro...

متن کامل

Gibbs' Paradox and the Definition of Entropy

Gibbs’ Paradox is shown to arise from an incorrect traditional definition of the entropy that has unfortunately become entrenched in physics textbooks. Among its flaws, the traditional definition predicts a violation of the second law of thermodynamics when applied to colloids. By adopting Boltzmann’s definition of the entropy, the violation of the second law is eliminated, the properties of co...

متن کامل

Gibbs Paradox and Stability of Porous Structure

When Maurice A. Biot developed the theory of fluid mixtures and stability of porous media, he recognized the difficulties posed by the Gibbs Paradox. Three of his papers are closely related to the resolution of Gibbs Paradox [1-3]. He is also well-known for the work on variational principles in thermodynamics [4]. When a porous medium is subjected to thermodynamic studies, "containers" of the f...

متن کامل

The free quon gas suffers Gibbs' paradox.

where f, g are test functions, i.e., elements of the oneparticle space with inner product 〈f, g〉, a(f) is a Hilbert space operator with adjoint a†(f) depending linearly on f . The deformation parameter q must be real, and we take it in the interval −1 < q < 1. At the endpoints of this interval the relations become the canonical commutation relations (q = 1), and the canonical anticommutation re...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ژورنال

عنوان ژورنال: Molecular Physics

سال: 2018

ISSN: 0026-8976,1362-3028

DOI: 10.1080/00268976.2018.1463467